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Biodegradable polymers are a type of biomaterial that can be broken down by natural processes in the body or the environment. They have many potential applications in the field of drug delivery and implants for tissue engineering applications, which aim to create artificial organs or tissues that can replace damaged ones. One of the advantages of biodegradable polymers is that they can be designed to form scaffolds, which are three-dimensional structures that support the growth of cells and tissues. The scaffolds can be programmed to degrade at a specific rate and time, so that they can gradually disappear as the new tissue grows and takes over their function [1]. The degradation of the scaffolds can happen through different mechanisms, depending on the type of polymer and the conditions of the environment. Some of the common mechanisms are physical or chemical processes, such as hydrolysis or oxidation, and biological processes, such as enzymatic digestion or phagocytosis by immune cells [234]. The degradation of the scaffolds can also affect their structure and properties in different ways. Some scaffolds undergo bulk degradation, which means that they break down evenly throughout their volume, resulting in a decrease in their molecular mass and mechanical strength [235]. Other scaffolds undergo surface degradation, which means that they break down only at their surface, resulting in a decrease in their size but not in their internal structure. These scaffolds tend to maintain their mechanical stability for a longer time, which can be beneficial for some tissue regeneration applications. The rate and extent of biodegradation of polymeric scaffolds depend on many factors related to the polymer itself and the environment. Some of the important factors are the chemical structure of the polymer, which determines the type and number of bonds that can be cleaved by hydrolysis or enzymes; the hydrophilicity or hydrophobicity of the polymer, which affects its solubility and interaction with water molecules; the crystalline or amorphous morphology of the polymer, which affects its order and flexibility; the glass transition temperature (Tg) of the polymer, which affects its mobility and susceptibility to degradation; the copolymer ratio of the polymer, which affects its composition and properties; and the molecular weight of the polymer, which affects its chain length and entanglement [236]. The ideal biodegradable scaffold should have a degradation rate that matches the growth rate of the tissue in vitro (in laboratory conditions) and in vivo (in living organisms), so that it can provide adequate support and guidance for tissue formation without causing adverse effects. On the other hand, nonbiodegradable polymeric scaffolds are those that do not degrade or degrade very slowly in biological environments. They are biologically stable and can provide a permanent support for tissues that need long-term mechanical function. For example, polymethyl methacrylate (PMMA) is a nonbiodegradable polymer that is widely used as bone cement in hip and knee replacements, where it acts as a filler and adhesive between the bone and the metal implant [13]. Another example is high-density polyethylene (HDPE), a nonbiodegradable polymer that is used to form the articulating surfaces of hip and knee joints, where it provides low friction and wear resistance [13]. 061ffe29dd